Articles | Volume 6, issue 1
https://doi.org/10.5194/soil-6-231-2020
https://doi.org/10.5194/soil-6-231-2020
Original research article
 | 
03 Jun 2020
Original research article |  | 03 Jun 2020

Catchment export of base cations: improved mineral dissolution kinetics influence the role of water transit time

Martin Erlandsson Lampa, Harald U. Sverdrup, Kevin H. Bishop, Salim Belyazid, Ali Ameli, and Stephan J. Köhler

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Cited articles

Aagaard P. and Helgeson, H.: Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions: I. Theoretical considerations, Am. J. Sci., 282, 237–285, 1982. 
Akselsson, C., Westling, O., Sverdrup, H., Holmqvist, J., Thelin, G., Uggla, E., and Malm, G.: Impact of harvest intensity on long-term base cation budgets in Swedish forest soils, Water Air Soil Poll., 7, 201–210, https://doi.org/10.1007/s11267-006-9106-6, 2007. 
Akselsson, C., Olsson, J., Belyazid, S., and Capell, R.: Can increased weathering rates due to future warming compensate for base cation losses following whole-tree harvesting in spruce forests?, Biogeochemistry, 128, 89–105, https://doi.org/10.1007/s10533-016-0196-6, 2016. 
Ameli, A. A., McDonnell, J. J., and Bishop, K.: The exponential decline in saturated hydraulic conductivity with depth: a novel method for exploring its effect on water flow paths and transit time distribution, Hydrol. Process., 30, 2438–2450, https://doi.org/10.1002/hyp.10777, 2016a. 
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Short summary
In this study, we demonstrate how new equations describing base cation release from mineral weathering can reproduce patterns in observations from stream and soil water. This is a major step towards modeling base cation cycling on the catchment scale, which would be valuable for defining the highest sustainable rates of forest harvest and levels of acidifying deposition.