Articles | Volume 11, issue 2
https://doi.org/10.5194/soil-11-535-2025
https://doi.org/10.5194/soil-11-535-2025
Original research article
 | 
17 Jul 2025
Original research article |  | 17 Jul 2025

Interplay of coprecipitation and adsorption processes: deciphering amorphous mineral–organic associations under both forest and cropland conditions

Floriane Jamoteau, Emmanuel Doelsch, Nithavong Cam, Clément Levard, Thierry Woignier, Adrien Boulineau, Francois Saint-Antonin, Sufal Swaraj, Ghislain Gassier, Adrien Duvivier, Daniel Borschneck, Marie-Laure Pons, Perrine Chaurand, Vladimir Vidal, Nicolas Brouilly, and Isabelle Basile-Doelsch

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Cited articles

Asano, M., Wagai, R., Yamaguchi, N., Takeichi, Y., Maeda, M., Suga, H., and Takahashi, Y.: In Search of a Binding Agent: Nano-Scale Evidence of Preferential Carbon Associations with Poorly-Crystalline Mineral Phases in Physically-Stable, Clay-Sized Aggregates, Soil Syst., 2, 32, https://doi.org/10.3390/soilsystems2020032, 2018. 
Bailey, V. L., Pries, C. H., and Lajtha, K.: What do we know about soil carbon destabilization?, Environ. Res. Lett., 14, 083004, https://doi.org/10.1088/1748-9326/ab2c11, 2019. 
Basile-Doelsch, I., Brun, T., Borschneck, D., Masion, A., Marol, C., and Balesdent, J.: Effect of landuse on organic matter stabilized in organomineral complexes: A study combining density fractionation, mineralogy and δ13C, Geoderma, 151, 77–86, https://doi.org/10.1016/j.geoderma.2009.03.008, 2009. 
Basile-Doelsch, I., Balesdent, J., and Rose, J.: Are Interactions between Organic Compounds and Nanoscale Weathering Minerals the Key Drivers of Carbon Storage in Soils?, Environ. Sci. Technol., 49, 3997–3998, https://doi.org/10.1021/acs.est.5b00650, 2015. 
Basile-Doelsch, I., Balesdent, J., and Pellerin, S.: Reviews and syntheses: The mechanisms underlying carbon storage in soil, Biogeosciences, 17, 5223–5242, https://doi.org/10.5194/bg-17-5223-2020, 2020. 
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Short summary
This study explores the impact of converting forests to agricultural land on soil C stabilization. By analyzing soil samples from a forest and crop Andosols, we found that C-stabilizing mineral–organic associations were in the form of amorphous coprecipitates in both soils. However, their quantity was significantly lower in the crop topsoil, suggesting their vulnerability to agricultural conversion. This highlights the need to develop strategies to preserve these associations in crop soils.
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