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  <front>
    <journal-meta><journal-id journal-id-type="publisher">SOIL</journal-id><journal-title-group>
    <journal-title>SOIL</journal-title>
    <abbrev-journal-title abbrev-type="publisher">SOIL</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">SOIL</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">2199-398X</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/soil-12-37-2026</article-id><title-group><article-title>An in-situ methodology to separate the  contribution of soil water content and salinity to EMI-based soil electrical conductivity</article-title><alt-title>Separating water content and salinity contributions in EMI data</alt-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2">
          <name><surname>Autovino</surname><given-names>Dario</given-names></name>
          <email>dario.autovino@unipa.it</email>
        <ext-link>https://orcid.org/0000-0001-5808-2000</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Coppola</surname><given-names>Antonio</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>De Mascellis</surname><given-names>Roberto</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Farzamian</surname><given-names>Mohammad</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9549-7344</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Basile</surname><given-names>Angelo</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-6238-0278</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Department of Agricultural, Food and Forest Sciences, University of Palermo, Palermo, 90128, Italy</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Institute for Mediterranean Agricultural and Forestry Systems,  National Research Council of Italy, Portici, 80055, Italy</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Department of Chemical and Geological Sciences, University of Cagliari, Monserrato, 09042, Italy</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Instituto Nacional de Investigação Agrária e Veterinária, Oeiras 2780-157, Portugal</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Dario Autovino (dario.autovino@unipa.it)</corresp></author-notes><pub-date><day>13</day><month>January</month><year>2026</year></pub-date>
      
      <volume>12</volume>
      <issue>1</issue>
      <fpage>37</fpage><lpage>54</lpage>
      <history>
        <date date-type="received"><day>6</day><month>June</month><year>2025</year></date>
           <date date-type="rev-request"><day>25</day><month>June</month><year>2025</year></date>
           <date date-type="rev-recd"><day>21</day><month>November</month><year>2025</year></date>
           <date date-type="accepted"><day>1</day><month>December</month><year>2025</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2026 Dario Autovino et al.</copyright-statement>
        <copyright-year>2026</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026.html">This article is available from https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026.html</self-uri><self-uri xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026.pdf">The full text article is available as a PDF file from https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d2e141">Salt accumulation in the root zone limits agricultural productivity and can eventually lead to land abandonment. Therefore, monitoring the spatial distribution of soil water content and solution salinity is crucial for effective land and irrigation management. However, assessing soil water content and salinity at the field scale is often challenging due to the heterogeneity of soil properties.</p>

      <p id="d2e144">Electromagnetic induction (EMI) offers a fast, non-invasive, in situ geophysical method to map spatial variability in soil. EMI instruments measure the apparent soil electrical conductivity (EC<sub>a</sub>), which reflects the integrated contribution of the bulk electrical conductivity (<inline-formula><mml:math id="M2" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) of different soil layers. By inverting the measured EC<sub>a</sub>, it is possible to obtain the distribution of the <inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> along the soil profile, which provides indirect information on soil salinity. However, in saline soils, <inline-formula><mml:math id="M5" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is influenced by both water content (<inline-formula><mml:math id="M6" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>) and soil solution electrical conductivity (<inline-formula><mml:math id="M7" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) (the salinity), making it difficult to independently quantify these two variables through a single, straightforward procedure.</p>

      <p id="d2e217">The objective of this study is to separate the respective contributions of <inline-formula><mml:math id="M8" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M9" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> to <inline-formula><mml:math id="M10" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, as obtained from the EMI inversion. To achieve this, EC<sub>a</sub> was measured using a CMD-MiniExplorer instrument in two maize plots irrigated with saline and non-saline water, respectively, in an agricultural field in southern Italy. The dataset was then inverted in order to obtain the <inline-formula><mml:math id="M12" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> distribution. By employing a site-specific calibrated Rhoades linear model and assuming pedological homogeneity between the two plots, the spatial distribution of <inline-formula><mml:math id="M13" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M14" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in the saline plot was successfully estimated. To validate the results, independent measurements of soil water content by Time Domain Reflectometry (TDR) and direct measurement of soil solution electrical conductivity, <inline-formula><mml:math id="M15" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, were performed.</p>

      <p id="d2e299">The proposed procedure enables the estimation of <inline-formula><mml:math id="M16" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M17" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> with high accuracy along the soil profile, except in the soil surface, where EMI reliability is limited. These findings demonstrate that the integration of EMI with a site-specific <inline-formula><mml:math id="M18" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M19" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> model is a reliable and efficient in-situ approach for mapping soil salinity and water content at field scale, offering valuable insights for optimizing agricultural irrigation management in systems using saline water.</p>
  </abstract>
    
<funding-group>
<award-group id="gs1">
<funding-source>Ministero delle Politiche Agricole Alimentari e Forestali</funding-source>
<award-id>SALTFREE: Salinization in irrigated areas: risk evaluation and prevention”, funded by the MIPAAF (Ministry of Agriculture) under the call ARIMNET2</award-id>
</award-group>
</funding-group>
</article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d2e358">Regions with hot, dry summers are often irrigated with low-quality saline water to alleviate water scarcity (Ghazouani et al., 2015; Tlig et al., 2023). However, this practice can lead to the accumulation of soluble salts in the root zone, causing soil salinization (Brouwer et al., 1985). Salt stress occurs when the osmotic potential decreases due to the presence of soluble salts in the soil solution, which inhibits water uptake by the roots (Coppola et al., 2015; Rasool et al., 2013). Hence, soil salinization is one of the most significant abiotic stresses affecting agriculture (de Oliveira et al., 2013).</p>
      <p id="d2e361">The Global Map of Salt-Affected Soils (<uri>https://www.fao.org/soils-portal/data-hub/soil-maps-and-databases/global-map-of-salt-affected-soils/ar/</uri>, last access: 22 December 2025) indicates that salt-affected soils are widespread globally, with around two-thirds of the affected areas located in arid and semi-arid climatic zones. It is estimated that salt-affected soils cover approximately 4.4 % of the topsoil (0–30 cm) and over 8.7 % of the subsoil (30–100 cm) of the total land area.</p>
      <p id="d2e367">Therefore, accurately assessing soil salinity and the distribution of soil water content (<inline-formula><mml:math id="M21" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>) is essential for managing irrigation with saline water while maintaining acceptable crop yields (Dragonetti et al., 2018; Selim et al., 2013). This approach helps preventing stress conditions that could limit crop productivity. The common method to evaluate field soil salinity is measuring the electrical conductivity of the soil solution (<inline-formula><mml:math id="M22" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) (Campbell et al., 1949). Different direct and indirect procedures can be used to measure <inline-formula><mml:math id="M23" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. In general, direct methods such as the gravimetric method for <inline-formula><mml:math id="M25" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and the soil extract method for <inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are accurate but non-reproducible and require significant effort and time for measuring <inline-formula><mml:math id="M27" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> distribution, making them impractical in most applicative cases. Time Domain Reflectometry (TDR) is a well-established non-destructive method for measuring soil dielectric permittivity (<inline-formula><mml:math id="M29" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>) and impedance (<inline-formula><mml:math id="M30" display="inline"><mml:mi>Z</mml:mi></mml:math></inline-formula>). This method allows for the simultaneous estimation of both soil water content (<inline-formula><mml:math id="M31" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>) from <inline-formula><mml:math id="M32" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula> and bulk electrical conductivity (<inline-formula><mml:math id="M33" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) from <inline-formula><mml:math id="M34" display="inline"><mml:mi>Z</mml:mi></mml:math></inline-formula> (Bouksila et al., 2008; Dalton et al., 1984; Noborio, 2001). <inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is influenced by several factors, including soil water content, electrical conductivity of the soil solution, the tortuosity of the soil-pore system, soil temperature, and other factors related to the solid phase, such as bulk density, clay content, and mineralogy (McNeill, 1980; Muñoz-Carpena et al., 2005). Over the past few decades, both physical and empirical approaches have been developed to estimate the relationship between the three key variables that fluctuate over time: <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M37" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values (Hilhorst, 2000; Malicki and Walczak, 1999; Mualem and Friedman, 1991; Nadler et al., 1984; Rhoades et al., 1976, 1989). By measuring two of the three quantities in this relationship, TDR remains a highly effective method for monitoring soil salinity.</p>
      <p id="d2e531">While TDR measurements and other direct methods offer advantages, they are limited to investigating small soil volumes at a restricted number of sites, making them suitable primarily for local-scale monitoring (Shanahan et al., 2015). In contrast, the Electromagnetic Induction (EMI) method provides fast and reliable estimations of <inline-formula><mml:math id="M39" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> over larger spatial scales (Robinet et al., 2018). This technique employs inductive coupling and has the benefit of requiring no direct contact with the soil surface (Mester et al., 2011). Additionally, EMI enables the rapid mapping of soil variability across extensive areas with high spatial resolution (Doolittle and Brevik, 2014).</p>
      <p id="d2e553">EMI sensors measure apparent electrical conductivity (EC<sub>a</sub>). EC<sub>a</sub> data does not represent the <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> at a single physical depth but rather a weighted, cumulative response of the soil column beneath the sensor. The sensitivity of each measurement depends on the transmitter-receiver spacing and the operating frequency, which determine the effective depth range to which the instrument is most responsive. For this reason, an inversion process is required to estimate a layered conductivity model whose forward response reproduces the measured EC<sub>a</sub> data. To extract the distribution of <inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> along soil profiles, the EC<sub>a</sub> values obtained by EMI sensors can be inverted using either a cumulative sensitivity approach (McNeill, 1980) or the full solution of Maxwell's equations (Mester et al., 2011). Lavoué et al. (2010) introduced a calibration technique to improve the accuracy of <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> measurements by incorporating data from Electrical Resistivity Tomography (ERT). Alternatively, multiple TDR observations can be used as an effective substitute for ERT when monitoring the root zone (Dragonetti et al., 2018).</p>
      <p id="d2e626">However, even when a reliable distribution of <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is obtained through the inversion of EMI-based EC<sub>a</sub> readings, distinguishing the individual contributions of water content (<inline-formula><mml:math id="M50" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>) and soil salinity (<inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) to these <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values remains a challenging task. Unlike TDR, EMI does not provide simultaneous measurements of water content, necessitating the development of alternative methods to isolate the influence of <inline-formula><mml:math id="M53" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> on the estimated <inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. In soils where salinity is low and relatively stable, a linear relationship between <inline-formula><mml:math id="M56" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> derived from EMI measurements can be effectively applied (Altdorff et al., 2018; Badewa et al., 2018; Brevik et al., 2006; Huang et al., 2016; Serrano et al., 2013). On the other hand, in saline soils where salt concentration is significant and varies over time and space, a sole <inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> measurement cannot simultaneously determine both <inline-formula><mml:math id="M59" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M60" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (Dragonetti et al., 2022; Farzamian et al., 2021).</p>
      <p id="d2e756">This study aims to develop an EMI-based methodology for estimating the field-scale evolution of <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> distribution in saline-irrigated soils. Specifically, it explores the potential of EMI measurements to distinguish soil water content from the bulk electrical conductivity of soil water within the EMI signal. By evaluating this approach under controlled conditions, its validity and limitations were assessed, providing a foundation for broader applications in soil monitoring and irrigation management. Further research needs were also identified to make the approach more feasible and relevant for precision agriculture applications.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Material and Methods</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Field experiment</title>
      <p id="d2e785">The experiment was conducted at the “Arca 2010” farm, located in Acerra municipality, approximately 20 km northeast of Naples, Italy (40°57<sup>′</sup>58<sup>′′</sup> N, 14°25<sup>′</sup>47<sup>′′</sup> E, 27 m a.s.l.) (see Fig. 1, top panel). The farm is situated in a flat area characterized by Mollic Vitric Andosols (IUSS Working Group WRB, 2015). The soil profile includes a topsoil layer from 0 to 40 cm and a subsoil layer from 40 to 110 cm, both with a sandy loam texture and high chemical and physical fertility (Bonfante et al., 2019). The climate is typically Mediterranean, with an average annual rainfall of 876 mm and an average annual temperature of 16.9 °C.</p>

      <fig id="F1" specific-use="star"><label>Figure 1</label><caption><p id="d2e832">Schematic view of the experimental field (top panel) and front view of the trench showing measurement points (bottom panel). Map of Italy source: <uri>https://en.wikipedia.org/wiki/Platania#/media/File:Italy_provincial_location_map_2016.svg</uri> (last access: 24 June 2025), licensed under CC BY-SA.</p></caption>
          <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f01.png"/>

        </fig>

      <p id="d2e844">Two plots of silage maize (Zea mays) were arranged in this field, each measuring 18 <inline-formula><mml:math id="M66" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 68 m, covering a total area of 1224 m<sup>2</sup> per plot. The maize was seeded on 16 April 2018 with a row spacing of 0.17 and 0.75 m between adjacent rows and harvested on 2 August 2018 (see Fig. 1, top panel).</p>
      <p id="d2e864">Irrigation was performed using a dripline system, consisting of thin-walled polyethylene pipes installed between adjacent plant rows. The system featured drippers spaced 10 cm apart, with a flow rate of 1.5 L h<sup>−1</sup>. Throughout the growing season, both plots received six irrigation treatments, each providing 490 (<inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">154</mml:mn></mml:mrow></mml:math></inline-formula>) m<sup>3</sup> ha<sup>−1</sup> of water on the same days.</p>
      <p id="d2e910">The irrigation water for the non-saline plot was supplied from a farm's well and had a background electrical conductivity of 1.6 dS m<sup>−1</sup> with no salt addition In contrast, for the saline plot, calcium chloride (CaCl<sub>2</sub>) was added to achieve an electrical conductivity of approximately 8 dS m<sup>−1</sup>.</p>
      <p id="d2e946">During the growing season, the leaf water potential, <inline-formula><mml:math id="M75" display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula>, was measured on nine dates between 11 June and 29 July 2018 (<inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula>) on a well expanded, fully light-exposed leaf for each plot using a Scholander type pressure bomb (SAPS II, 3115, Soilmoisture Equipment Corp., Santa Barbara CA, USA). After cutting, the leaf was promptly inserted in the pressure bomb, where pressure was increased at a rate of 0.2 MPa min<sup>−1</sup> to determine <inline-formula><mml:math id="M78" display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula>.</p>
      <p id="d2e987">On 2 August, after maize harvesting, apparent soil electrical conductivity (EC<sub>a</sub>) measurements were taken on both plots using the CMD Mini-Explorer (GF Instruments, Brno, Czech Republic). This device incorporates three receiver coils positioned at specific distances of 0.32 m (<inline-formula><mml:math id="M80" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32), 0.71 m (<inline-formula><mml:math id="M81" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71), and 1.18 m (<inline-formula><mml:math id="M82" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118) from the transmitter coil, operating at a fixed frequency of 30 kHz. Two coil configurations were utilised with this probe: horizontal coplanar (HCP) and vertical coplanar (VCP) loops. In HCP mode, the instrument's effective depth of investigation is approximately 0.5, 1.0, and 1.8 m for the <inline-formula><mml:math id="M83" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32, <inline-formula><mml:math id="M84" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71, and <inline-formula><mml:math id="M85" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118 coil spacings respectively, whereas VCP mode allows for shallower depth of investigation – approximately half that of the HCP configuration – probing depths of up to 0.25, 0.50, and 0.90 m at the corresponding <inline-formula><mml:math id="M86" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32, <inline-formula><mml:math id="M87" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71, and <inline-formula><mml:math id="M88" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118 coil spacings. This suggests that the instrument offers high vertical resolution for resolving features within the upper 1 m of the subsurface, due to the presence of multiple, closely-spaced measurement points (0.25, 0.5, and 0.9 m effective depths in VCP mode; 0.5 and 1.0 m in HCP mode). The resolution decreases significantly for depths exceeding 1 m because only a single sensor spacing provides data within that deeper range (1.8 m effective depth in HCP mode).</p>
      <p id="d2e1063">Measurements were acquired along a 17 m-long transect, located centrally in each plot (see Fig. 1, top panel) restricted between two adjacent crop rows to minimize disturbance and avoid spatial aliasing.</p>
      <p id="d2e1066">On the same day, following the EMI measurements, a 17 m trench was excavated in the saline plot to a depth of 1.4 m, directly along the EMI transect. TDR probes were inserted into 17 vertical profiles within the trench, spaced 1 m apart and positioned at four depths (15, 50, 75, and 90 cm), resulting in a total of 68 measurement points (see Fig. 1, bottom panel). For each point, the Tektronix 1502 C cable tester was used to analyse the acquired wave, measuring the dielectric permittivity (<inline-formula><mml:math id="M89" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>) and impedance (<inline-formula><mml:math id="M90" display="inline"><mml:mi>Z</mml:mi></mml:math></inline-formula>) over a long time to estimate soil moisture content (<inline-formula><mml:math id="M91" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>) and bulk electrical conductivity (<inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), respectively. This co-location ensured that the surveys referred to the same position as the EMI inversion along the 17 m line.</p>
      <p id="d2e1102">Notably, TDR measurements were performed in the same positions where time-lapse EMI measurements were previously made, so as to have reference, point-scale values of soil water content and bulk electrical conductivity. Finally, 68 disturbed soil samples were collected in the same locations where TDR measurements were performed to determine soil-solution electrical conductivity (<inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>).</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>EMI and TDR analysis</title>
      <p id="d2e1129">The vertical distribution of bulk electrical conductivity (<inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>z</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>) was obtained by inverting the EC<sub>a</sub> dataset using EM4SOIL software (Triantafilis et al., 2013) by applying a 1-D laterally constrained method developed by Monteiro Santos (2004). The inversion algorithm employs a set of 1D conductivity models constrained by their neighbours, with forward modelling based on the full solution of Maxwell's equations (Kaufman and Keller, 1983). All models used in the inversion have the same number of layers, and the thickness of these layers is kept constant.</p>
      <p id="d2e1158">Occam regularization (deGroot-Hedlin and Constable, 1990) and the S2 inversion algorithm (Sasaki, 2001) were utilized in this study. Occam regularization helps to stabilize the inversion process by constraining model variations around a reference model, making the results less sensitive to noisy data. The balance between data fit and neighbour constraints during inversion is controlled by an empirical multiplier (or damping factor). During the inversion process, damping factors values, <inline-formula><mml:math id="M96" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> decrease gradually to resolve more detailed parameters (e.g., Farzamian et al., 2019). Inversion results will generally be smoother if the values are larger. The best inversion parameters are usually achieved empirically after testing various parameter sets. In this study, the maximum number of iterations was set to 10, and the damping factor was set to 0.5.</p>
      <p id="d2e1168">The TDR technique, utilized for both field and laboratory measurements, allows for the estimation of <inline-formula><mml:math id="M97" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d2e1189">Soil water content is estimated by determining the soil permittivity using the TDR (Tektronix 1502 C), which measures the propagation time of electromagnetic waves generated by the pulse generator and detected by a sampling oscilloscope (Noborio, 2001). Permittivity (<inline-formula><mml:math id="M99" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>) is calculated based on the propagation velocity (<inline-formula><mml:math id="M100" display="inline"><mml:mi>v</mml:mi></mml:math></inline-formula>) of the electromagnetic waves, as described by:

            <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M101" display="block"><mml:mrow><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>=</mml:mo><mml:msup><mml:mfenced open="(" close=")"><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi>c</mml:mi><mml:mi>v</mml:mi></mml:mfrac></mml:mstyle></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:msup><mml:mfenced close=")" open="("><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi>c</mml:mi><mml:mo>⋅</mml:mo><mml:mi>t</mml:mi></mml:mrow><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mi>L</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></disp-formula>

          where <inline-formula><mml:math id="M102" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> is the velocity of electromagnetic waves in a vacuum (<inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">8</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> m s<sup>−1</sup>), <inline-formula><mml:math id="M105" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> is the round-trip time for the pulse to traverse the length of the probe (down and back: <inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mi>L</mml:mi></mml:mrow></mml:math></inline-formula>) [s], <inline-formula><mml:math id="M107" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> is the TDR probe length [m].</p>
      <p id="d2e1306">The measurement of <inline-formula><mml:math id="M108" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is based on the attenuation of the voltage pulse magnitude (Dalton et al., 1984). The TDR Tektronix 1502 C measures the total resistance, <inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">T</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, of the transmission line using:

            <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M110" display="block"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">T</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>Z</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi></mml:mrow></mml:mfenced></mml:mrow><mml:mrow><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi></mml:mrow></mml:mfenced></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></disp-formula>

          where: <inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the series resistance from the cable and connector [<inline-formula><mml:math id="M112" display="inline"><mml:mi mathvariant="normal">Ω</mml:mi></mml:math></inline-formula>], <inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the soil contribution to the total resistance [<inline-formula><mml:math id="M114" display="inline"><mml:mi mathvariant="normal">Ω</mml:mi></mml:math></inline-formula>], <inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:msub><mml:mi>Z</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the characteristic impedance of the transmission line (50 <inline-formula><mml:math id="M116" display="inline"><mml:mi mathvariant="normal">Ω</mml:mi></mml:math></inline-formula> in this case), <inline-formula><mml:math id="M117" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula> is the voltage reflection coefficient at a large travel time, when the signal reflected at the end of the probe reaches a constant value (Comegna et al., 2017).</p>
      <p id="d2e1445">The <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> at 25 °C can be calculated as (Rhoades and Van Schilfgaarde, 1976) <inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:mo>/</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mi>T</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the geometric (cell) constant of the TDR probe and <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi>T</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is a temperature correction factor to be used for values measured at temperatures other than 25 °C. Both <inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> can be determined in the laboratory by measuring <inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi>T</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> by TDR in a solution with known salinity.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Laboratory analysis</title>
<sec id="Ch1.S2.SS3.SSS1">
  <label>2.3.1</label><title>Soil-specific <inline-formula><mml:math id="M125" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship</title>
      <p id="d2e1577">The poorly crystalline clay minerals of Andosols present at the experimental site significantly affect soil dielectric response (Bartoli et al., 2007; Regalado et al., 2003). Consequently, although Topp et al.'s (1980) <inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship is generally applicable to most mineral soils, site-specific polynomial relationships were developed for the topsoil and subsoil to ensure accurate soil water content estimation.</p>
      <p id="d2e1594">To obtain the soil-specific <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship for the investigated soil, preliminarily two PVC cylinders, each with a diameter of 8 cm and a height of 15 cm, were almost filled with air-dried soil to achieve a bulk density of approximately 1.1 g cm<sup>−3</sup>, similar to that of undisturbed soil and a 12 cm long TDR probe was inserted from the top. Then, the soils columns were saturated slowly from the bottom to minimize air entrapment without disturbing packing and allowed complete saturation of the porous media.</p>
      <p id="d2e1623">To span a wide range of water contents, the columns were then allowed to evaporate at room temperature between measurement cycles. After each evaporation interval, the surface was covered with a thin polyethylene film for one day to promote hydraulic gradient equilibration and the measurements were taken only after this period. At each measurement cycle, a TDR signal was acquired to obtain <inline-formula><mml:math id="M129" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>, then the column was immediately weighed, and the film was removed to begin the next evaporation–equilibration cycle. Because TDR integrates along the 10–12 cm rod length, any residual vertical micro-gradients within that domain are effectively averaged (Ferré et al., 1996; Noborio, 2001). At the end of the sequence of 18 measurements, samples were oven-dried at 105 °C for 24 h to determine volumetric water content (<inline-formula><mml:math id="M130" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>).</p>
      <p id="d2e1641">Finally, the resulting <inline-formula><mml:math id="M131" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">ε</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> pairs were fitted to a linear relationship <inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="italic">α</mml:mi><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:mo>√</mml:mo><mml:mi mathvariant="italic">ε</mml:mi></mml:mrow></mml:math></inline-formula>, separately for the Ap and Bw horizons.</p>
</sec>
<sec id="Ch1.S2.SS3.SSS2">
  <label>2.3.2</label><title>Soil-specific <inline-formula><mml:math id="M134" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship</title>
      <p id="d2e1708">To determine the soil specific <inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship, preliminarily four undisturbed soil samples were collected from the non-saline plot using PVC cylinders (8 cm in diameter and 15 cm in height) to preserve field structure and bulk density. To span different salinity and soil water content, each air-dry sample was subjected to repeated top-wetting increments of 15 mL of CaCl<sub>2</sub> solution at specified electrical conductivities of: 1, 3, 6, and 9 dS m<sup>−1</sup>. The solution was applied uniformly from the top of the soil core surface and after each increment the sample was covered with 0.05 mm polyethylene film and the core was allowed to equilibrate overnight to promote capillary redistribution of water and solute. This wetting-equilibration procedure was repeated about 20 times for each soil sample to cover a wide range of soil water content values, from air-dry (<inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>≈</mml:mo><mml:mn mathvariant="normal">0.06</mml:mn></mml:mrow></mml:math></inline-formula> cm<sup>3</sup> cm<sup>−3</sup>) to near saturation (<inline-formula><mml:math id="M141" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>≈</mml:mo><mml:mn mathvariant="normal">0.46</mml:mn></mml:mrow></mml:math></inline-formula> cm<sup>3</sup> cm<sup>−3</sup>) with increases in water content of approximately 0.02 cm<sup>3</sup> cm<sup>−3</sup> for each application. For each sample, the procedure was stopped when the application volume led to visible drainage of the soil solution from the bottom of the cylinder.</p>
      <p id="d2e1837">For each soil sample, at the beginning of the experiment, a three-wire TDR probes (10 cm long with a rod diameter of 0.3 cm and rod spacing of 1.2 cm) was vertically inserted into the soil columns. Measurements of volumetric water content (<inline-formula><mml:math id="M146" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>) were taken using the topsoil-specific <inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationships, and bulk electrical conductivity (<inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) was also measured, based on the TDR impedance, <inline-formula><mml:math id="M149" display="inline"><mml:mi>Z</mml:mi></mml:math></inline-formula>, obtained at large signal travel times (e.g., Robinson et al., 2003).</p>
      <p id="d2e1879">The <inline-formula><mml:math id="M150" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M151" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> relationship calibration was obtained by ordinary least squares on the low-salinity subset (<inline-formula><mml:math id="M152" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>≈</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> dS m<sup>−1</sup>) and restricted to the medium-to-high <inline-formula><mml:math id="M154" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> range, representative of irrigation-season conditions, to avoid the known non-linearity and reduced sensitivity at low <inline-formula><mml:math id="M155" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>. Given the overall soil homogeneity, an unique linear fits <inline-formula><mml:math id="M156" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>=</mml:mo><mml:mi>a</mml:mi><mml:mo>+</mml:mo><mml:mi>b</mml:mi><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> were derived for whole profile.</p>
</sec>
<sec id="Ch1.S2.SS3.SSS3">
  <label>2.3.3</label><title>Calibration of the Rhoades <inline-formula><mml:math id="M157" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M158" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M159" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> model</title>
      <p id="d2e2002">Rhoades et al. (1976) proposed a linear model between <inline-formula><mml:math id="M160" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M161" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> for a given <inline-formula><mml:math id="M162" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> value:

              <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M163" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">θ</mml:mi><mml:mi>T</mml:mi><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></disp-formula>

            were <inline-formula><mml:math id="M164" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> is the transmission coefficient, also known as tortuosity, which considers the tortuous nature of the current line and any decrease in the mobility of the solid-liquid and liquid-gas interfaces, whereas <inline-formula><mml:math id="M165" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represents the electrical conductivity of the solid phase of the soil that is associated to the exchangeable ions in the solid-liquid interface.</p>
      <p id="d2e2082">Tortuosity linearly depends on <inline-formula><mml:math id="M166" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and is characterised as follows:

              <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M167" display="block"><mml:mrow><mml:mi>T</mml:mi><mml:mo>=</mml:mo><mml:mi>a</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>+</mml:mo><mml:mi>b</mml:mi></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M168" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M169" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> are parameters specific for each soil type estimated as a fitting parameter in Eq. (3). <inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is calculated using a graphical approach (Rhoades et al., 1976).</p>
      <p id="d2e2136">In order to calibrate the Rhoades model for deriving the soil-specific <inline-formula><mml:math id="M171" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M172" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M173" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameters, the procedure was performed separately for Ap and Bw soils, using the undisturbed cores and the stepwise wetting protocol described in Sect. 2.3.2 (CaCl<sub>2</sub> solutions at <inline-formula><mml:math id="M175" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>, 3, 6, 9 dS m<sup>−1</sup>; room temperature). This “increment-and-equilibrate” approach mirrors standard TDR laboratory practice for jointly acquiring <inline-formula><mml:math id="M177" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M178" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> on the same volume and at stable moisture/salinity states as reported in Malicki and Walczak (1999) Finally, the obtained <inline-formula><mml:math id="M179" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M180" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M181" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> data were fitted to the Rhoades model to finalize the calibration procedure. To do this, parameters (<inline-formula><mml:math id="M182" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M183" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M184" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) were estimated by nonlinear least squares (Levenberg–Marquardt), minimizing the sum of squared residuals between measured and predicted <inline-formula><mml:math id="M185" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values. Non-negativity constraints were imposed <inline-formula><mml:math id="M186" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>≥</mml:mo></mml:mrow></mml:math></inline-formula>0. The best-fit coefficients of the calibration procedure (RMSE an <inline-formula><mml:math id="M187" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>) are reported Table 1.</p>
</sec>
<sec id="Ch1.S2.SS3.SSS4">
  <label>2.3.4</label><title>Soil solution electrical conductivity determination</title>
      <p id="d2e2317">The soil solution electrical conductivity (<inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) was determined on 1 , 2 volume extract method (Rhoades et al., 1999). The 68 disturbed soil samples collected from the trench were preliminary air dried at room temperature, crumbled and sieved through a 2 mm mesh to remove coarse fragments and roots before extraction. Subsequently, for each sample, a 1 : 2 soil-to-water suspensions were prepared using 50 g of soil and 100 mL of distilled water. Once the soil and water were combined, the suspension was stirred thoroughly to ensure the full dissolution of the soluble salt into the water. After mixing, the suspension was centrifuged to separate the solid particles from the liquid phase, allowing extract the soil solution. Finally, the electrical conductivity of the extracted soil solutions was measured using a calibrated EC meter (Alves et al., 2022). Subsequently, chloride concentration in the extracts was determined via titration (Mohr's Method). A linear regression model was then established between the measured electrical conductivity (<inline-formula><mml:math id="M189" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) and the corresponding chloride concentration, resulting in an empirical relationship of the form:

              <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M190" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.0028</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mfenced open="[" close="]"><mml:mrow><mml:msup><mml:mi mathvariant="normal">Cl</mml:mi><mml:mo>-</mml:mo></mml:msup></mml:mrow></mml:mfenced><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.068</mml:mn></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M191" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the electrical conductivity of extract (dS m<sup>−1</sup>), <inline-formula><mml:math id="M193" display="inline"><mml:mrow><mml:mfenced open="[" close="]"><mml:mrow><mml:msup><mml:mi mathvariant="normal">Cl</mml:mi><mml:mo>-</mml:mo></mml:msup></mml:mrow></mml:mfenced></mml:mrow></mml:math></inline-formula> is the chloride concentration (mg L<sup>−1</sup>).</p>
      <p id="d2e2438">To estimate the electrical conductivity representative of field conditions, the chloride concentration was scaled to the measured soil water content (SWC) of each sample. The scaled chloride concentration was calculated as the ratio between the total chloride mass and the water mass in the soil sample. Finally, the scaled <inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:mfenced open="[" close="]"><mml:mrow><mml:msup><mml:mi mathvariant="normal">Cl</mml:mi><mml:mo>-</mml:mo></mml:msup></mml:mrow></mml:mfenced></mml:mrow></mml:math></inline-formula> was used in Eq. (5) to estimate the electrical conductivity, representative of the soil solution under its field water content conditions (<inline-formula><mml:math id="M196" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>).</p>
</sec>
</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>A synthesis of the applied procedure</title>
      <p id="d2e2479">The flowchart of the proposed procedure is displayed in Fig. 2 and summarized in the following six steps: <list list-type="custom"><list-item><label>1.</label>
      <p id="d2e2484"><italic>Irrigation and EMI Measurements</italic>: Two adjacent maize plots, were irrigated with saline and plain water, respectively. EMI measurements were performed along a 17-transect in middle of each plot in order to obtain the distribution of the EC<sub>a</sub> within the two plots.</p></list-item><list-item><label>2.</label>
      <p id="d2e2499"><italic>Inversion of EC</italic><sub><italic>a</italic></sub> <italic>to obtain</italic> <inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi>b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>: The <inline-formula><mml:math id="M200" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> distribution in both plots was calculated using the inversion procedure, detailed in Sect. 2.2.</p></list-item><list-item><label>3.</label>
      <p id="d2e2538"><italic>Soil-specific laboratory calibrations</italic>
<list list-type="custom"><list-item><label>i.</label>
      <p id="d2e2545"><inline-formula><mml:math id="M201" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship: A relationship <inline-formula><mml:math id="M202" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> was determined in laboratory on non-saline soil comparing soil-specific <inline-formula><mml:math id="M203" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M204" display="inline"><mml:mrow><mml:mo>√</mml:mo><mml:mi mathvariant="italic">ε</mml:mi></mml:mrow></mml:math></inline-formula> relations with the Topp et al. (1980) polynomial and the Ferré linearization.</p></list-item><list-item><label>ii.</label>
      <p id="d2e2593"><inline-formula><mml:math id="M205" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship: A linear calibration of <inline-formula><mml:math id="M206" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M207" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> relationship was determined on soil from the non-saline plot.</p></list-item><list-item><label>iii.</label>
      <p id="d2e2631">Rhoades <inline-formula><mml:math id="M208" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M209" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M210" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> model: A <inline-formula><mml:math id="M211" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M212" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M213" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> Rhoades et al. (1976) model parameters <inline-formula><mml:math id="M214" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M215" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M216" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> were estimated from laboratory dataset separately for the two horizons.</p></list-item></list></p></list-item><list-item><label>4.</label>
      <p id="d2e2719"><italic>Determination of</italic> <inline-formula><mml:math id="M217" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> <italic>distribution in non-saline plot</italic>: The inverted <inline-formula><mml:math id="M218" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> dataset obtained from the non-saline plot (Step 2) was converted in <inline-formula><mml:math id="M219" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> by the horizon-specific <inline-formula><mml:math id="M220" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M221" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> relation (Step 3-ii).</p></list-item><list-item><label>5.</label>
      <p id="d2e2772"><italic>Estimation of</italic> <inline-formula><mml:math id="M222" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi>w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <italic>in the saline plot</italic>: The inverted <inline-formula><mml:math id="M223" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> dataset from the saline allowed to estimate <inline-formula><mml:math id="M224" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> using the Rhoades et al. (1976) model and the average soil water content determined in the step 4. This estimation was based on the assumption that the mean and the variance of the soil water content distribution were similar in both plots.</p></list-item><list-item><label>6.</label>
      <p id="d2e2814"><italic>Validation of</italic> <inline-formula><mml:math id="M225" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi>w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <italic>and</italic> <inline-formula><mml:math id="M226" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>
<list list-type="custom"><list-item><label>i.</label>
      <p id="d2e2842">The <inline-formula><mml:math id="M227" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values estimated using the described procedure were validated by comparison to an independent <inline-formula><mml:math id="M228" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> dataset obtained in the laboratory through soil solution electrical conductivity (EC) measurements on disturbed soil samples (<inline-formula><mml:math id="M229" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>).</p></list-item><list-item><label>ii.</label>
      <p id="d2e2884">The <inline-formula><mml:math id="M230" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> values estimated by EMI were validated by comparing the soil water content measured with TDR in the saline plot.</p></list-item></list> The reliability of the estimates was analysed based on root mean square values (Root Mean Square Error, RMSE) and the mean deviation (Bias), according to the following formulas:<disp-formula specific-use="gather" content-type="numbered"><mml:math id="M231" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E6"><mml:mtd><mml:mtext>6</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mi mathvariant="normal">RMSE</mml:mi><mml:mo>=</mml:mo><mml:mroot><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:munderover><mml:msup><mml:mfenced open="(" close=")"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mo>,</mml:mo><mml:mi>i</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>X</mml:mi><mml:mrow><mml:mi mathvariant="normal">es</mml:mi><mml:mo>,</mml:mo><mml:mi>i</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow><mml:mi>N</mml:mi></mml:mfrac></mml:mstyle><mml:mn mathvariant="normal">2</mml:mn></mml:mroot></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E7"><mml:mtd><mml:mtext>7</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mi mathvariant="normal">Bias</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:mi>i</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>n</mml:mi></mml:munderover><mml:mo>(</mml:mo><mml:msub><mml:mi>X</mml:mi><mml:mrow><mml:mi mathvariant="normal">es</mml:mi><mml:mo>,</mml:mo><mml:mi>i</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>X</mml:mi><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mo>,</mml:mo><mml:mi>i</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow><mml:mi>N</mml:mi></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>where <inline-formula><mml:math id="M232" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are the measured values, <inline-formula><mml:math id="M233" display="inline"><mml:mrow><mml:msub><mml:mi>X</mml:mi><mml:mi mathvariant="normal">es</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are the estimated values at the time <inline-formula><mml:math id="M234" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M235" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> is the number of measured values.</p></list-item></list></p>

      <fig id="F2"><label>Figure 2</label><caption><p id="d2e3052">Flowchart of the proposed procedure.</p></caption>
          <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f02.png"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results and Discussion</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Field EC<sub>a</sub> acquisition in the non-saline plot [Step 2]</title>
      <p id="d2e3087">Figure 3 reports the spatial distribution of the measured apparent soil electrical conductivity (EC<sub>a</sub>) under VCP configuration (a) and HCP configuration (b) for the three receiver coils <inline-formula><mml:math id="M238" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32, <inline-formula><mml:math id="M239" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71, and <inline-formula><mml:math id="M240" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118. The EC<sub>a</sub> values are generally low, ranging from 0.02 to 0.08 dS m<sup>−1</sup>. The EC<sub>a</sub> data exhibit a similar pattern in both VCP and HCP modes, with slightly higher EC<sub>a</sub> values at <inline-formula><mml:math id="M245" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118, intermediate values at <inline-formula><mml:math id="M246" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71, and lower values at <inline-formula><mml:math id="M247" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32. This trend suggests a more conductive zone at deeper layers. In terms of horizontal variability, the EC<sub>a</sub> in vertical mode shows relatively small variation, with coefficients of variation of 15 %, 14 %, and 13 % for <inline-formula><mml:math id="M249" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118, <inline-formula><mml:math id="M250" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71, and <inline-formula><mml:math id="M251" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32, respectively. Even lower are the coefficients of variation in horizontal mode. Looking at the transect in Fig. 6a, an anomalous behaviour is revealed between 4.8 and 6.4 m. This anomaly is attributed to an old buried channel crossing the plot, which was uncovered during the excavation of the trench along the transect. Although the soil within the channel, formed over more than 80 years, had undergone pedogenesis and appeared similar to the surrounding soil, the channel's contours remain distinct and recognizable.</p>

      <fig id="F3" specific-use="star"><label>Figure 3</label><caption><p id="d2e3214">Apparent soil electrical conductivity (EC<sub>a</sub>) along the transect for the non-saline plot: <bold>(a)</bold> HCP mode; <bold>(b)</bold> VCP mode. Points indicate measured EC<sub>a</sub>, while dashed lines show the calculated EC<sub>a</sub> (forward response of the inversion). <bold>(c)</bold> Inversion results showing the bulk electrical conductivity (<inline-formula><mml:math id="M255" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) distribution with depth.</p></caption>
          <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f03.png"/>

        </fig>

      <p id="d2e3271">Figure 3c presents the modelling results with estimation of <inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> distribution with depth, down to 1.2 m, along the profile. The maximum depth for the presented model was selected based on the expected vertical resolution of the sensor (see Sect. 2.2) and investigation depth of interest where supporting data were available. The model response was shown in Fig. 3a, b by dashed lines. The misfit error is 0.01 dS m<sup>−1</sup>, indicating a fairly good fit between the observed data and model responses. In terms of vertical variability, the <inline-formula><mml:math id="M258" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values follow the trend of the observed data, showing a general increase with depth. This pattern suggests the presence of at least three distinct electrical layers, each with unique electrical and electromagnetic properties:</p>
      <p id="d2e3309">In the surface layer (0–30 cm), electrical conductivity exhibits medium-to-high values (0.03–0.08 dS m<sup>−1</sup>), likely due to a combination of factors. These include low soil water content during the EMI measurement and a slight increase in salt concentration in the pore water caused by evaporation from the soil surface, which is wetted by surface drip irrigation. Furthermore, as reported by Bonfante et al. (2019), who studied the same soil, the upper layer has a higher clay content (10.5 %) compared to the underlying layers. Given the well-established strong correlation between EC<sub>a</sub> and clay content (Sudduth et al., 2005), it is reasonable to hypothesize that the clay content could influence the observed EC<sub>a</sub> patterns in this surface layer.</p>
      <p id="d2e3342">The central layer (30–80 cm) is characterized by a minimum in <inline-formula><mml:math id="M262" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values forming a gradient that decreases from the top to the bottom of this layer. This zone is wetted by downward percolation (wetting bulb) from the drip surface irrigation, coinciding with peak root activity and also a decrease in clay content from 5.9 % to 3.9 % (Bonfante et al., 2019). Moreover, this layer is likely affected by downward leaching of salts and fertilizers toward deeper layers with drip irrigation water (Corwin et al., 2022).</p>
      <p id="d2e3356">The third and deepest layer (below 90 cm) is characterized by a progressive increase in bulk electrical conductivity. This can be explained by the highest clay content in soil profile (11.6 %), combined with an increase in soil compaction with depth that reduces water storage capacity, related to the reduction of porosity in this zone.</p>
      <p id="d2e3359">Regarding lateral variability, the overall variability remains low across all depths, except for the zone corresponding to the old channel, which is clearly distinguishable. The presence of this channel likely contributes to localized differences in soil properties, (such as the bulk density), creating distinct pattern in the electrical conductivity profile.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Laboratory experiments</title>
<sec id="Ch1.S3.SS2.SSS1">
  <label>3.2.1</label><title>Soil-specific <inline-formula><mml:math id="M263" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship [Step 3.i]</title>
      <p id="d2e3392">Table 1 presents the coefficients <inline-formula><mml:math id="M264" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M265" display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula> for the linear soil-specific relationship <inline-formula><mml:math id="M266" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="italic">α</mml:mi><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:mo>√</mml:mo><mml:mi mathvariant="italic">ε</mml:mi></mml:mrow></mml:math></inline-formula>, along with the coefficient of determination (<inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>) for both topsoil (Ap horizon) and subsoil (Bw horizon), obtained from laboratory experiments. The equations for the Ap horizon and Bw horizon show similar intercepts but slightly different slopes, leading to a divergence between the two curves at higher soil water contents.</p>

<table-wrap id="T1" specific-use="star"><label>Table 1</label><caption><p id="d2e3443">Coefficients and <inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> values for the <inline-formula><mml:math id="M269" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:mo>√</mml:mo><mml:mi mathvariant="italic">ε</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M271" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M272" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M273" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M274" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M275" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> soil-specific calibration relationships</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="13">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right" colsep="1"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right" colsep="1"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:colspec colnum="12" colname="col12" align="right"/>
     <oasis:colspec colnum="13" colname="col13" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Horizon</oasis:entry>
         <oasis:entry colname="col2">Depth</oasis:entry>
         <oasis:entry colname="col3">Texture</oasis:entry>
         <oasis:entry namest="col4" nameend="col6" align="center" colsep="1">Relationship (i) </oasis:entry>
         <oasis:entry namest="col7" nameend="col9" align="center" colsep="1">Relationship (ii) </oasis:entry>
         <oasis:entry namest="col10" nameend="col13" align="center">Rhoades model (iii) </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">[cm]</oasis:entry>
         <oasis:entry colname="col3"/>
         <oasis:entry rowsep="1" namest="col4" nameend="col6" align="center" colsep="1"><inline-formula><mml:math id="M278" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="italic">α</mml:mi><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:mo>√</mml:mo><mml:mi mathvariant="italic">ε</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry rowsep="1" namest="col7" nameend="col9" align="center" colsep="1"><inline-formula><mml:math id="M279" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>=</mml:mo><mml:mi>a</mml:mi><mml:mo>+</mml:mo><mml:mi>b</mml:mi><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry rowsep="1" namest="col10" nameend="col13" align="center"><inline-formula><mml:math id="M280" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M281" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M282" display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M283" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M284" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M285" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M286" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M287" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M288" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col12"><inline-formula><mml:math id="M289" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula><sup>∗</sup></oasis:entry>
         <oasis:entry colname="col13"><inline-formula><mml:math id="M291" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Ap</oasis:entry>
         <oasis:entry colname="col2">0–40</oasis:entry>
         <oasis:entry colname="col3">Loam</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M292" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.133</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5">0.113</oasis:entry>
         <oasis:entry colname="col6">0.96</oasis:entry>
         <oasis:entry colname="col7">0.178</oasis:entry>
         <oasis:entry colname="col8">0.726</oasis:entry>
         <oasis:entry colname="col9">0.94</oasis:entry>
         <oasis:entry colname="col10">1.32</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M293" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.14</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col12">0.13</oasis:entry>
         <oasis:entry colname="col13">0.95</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Bw</oasis:entry>
         <oasis:entry colname="col2">40–110</oasis:entry>
         <oasis:entry colname="col3">Sandy loam</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M294" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.130</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5">0.119</oasis:entry>
         <oasis:entry colname="col6">0.94</oasis:entry>
         <oasis:entry colname="col7">0.178</oasis:entry>
         <oasis:entry colname="col8">0.726</oasis:entry>
         <oasis:entry colname="col9">0.94</oasis:entry>
         <oasis:entry colname="col10">1.28</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M295" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.12</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col12">0.07</oasis:entry>
         <oasis:entry colname="col13">0.97</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d2e3522"><sup>*</sup> [dS m<sup>−1</sup>].</p></table-wrap-foot></table-wrap>

      <p id="d2e3930">Figure 4 compares the two observed relationships with the linear form of Topp's equation. The findings indicate that Topp's equation consistently overestimates the water content, with an average overestimation of approximately 0.07 <inline-formula><mml:math id="M296" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01 cm<sup>3</sup> cm<sup>−3</sup> in the Ap horizon and about 0.05 <inline-formula><mml:math id="M299" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02 cm<sup>3</sup> cm<sup>−3</sup> in the Bw horizon. These discrepancies suggest that the application of Topp's equation may require local calibration to account for horizon-specific characteristics.</p>

      <fig id="F4"><label>Figure 4</label><caption><p id="d2e3993">Soil specific linear relationship between the square root of relative dielectric permittivity and volumetric soil water content for the Ap and Bw horizons.</p></caption>
            <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f04.png"/>

          </fig>

</sec>
<sec id="Ch1.S3.SS2.SSS2">
  <label>3.2.2</label><title>Soil-specific <inline-formula><mml:math id="M302" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> relationship [Step 3.ii]</title>
      <p id="d2e4028">Figure 5 shows the soil-specific linear calibration between soil water content and bulk soil electrical conductivity <inline-formula><mml:math id="M303" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>=</mml:mo><mml:mi>a</mml:mi><mml:mo>+</mml:mo><mml:mi>b</mml:mi><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, with separate fit for the Ap and Bw horizons. Table 1 shows the corresponding coefficients of the relationship, along with the coefficients of determination (<inline-formula><mml:math id="M304" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>).</p>

      <fig id="F5"><label>Figure 5</label><caption><p id="d2e4065">Soil specific linear relationship between the <inline-formula><mml:math id="M305" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and volumetric soil water content for whole soil profile. The filled circle indicates the <inline-formula><mml:math id="M306" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M307" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> pairs from measured values, the dotted line represents the linear regression while the circles whit the white background are the pairs excluded from the calibration of the linear relationship.</p></caption>
            <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f05.png"/>

          </fig>

</sec>
<sec id="Ch1.S3.SS2.SSS3">
  <label>3.2.3</label><title>Calibration of the Rhoades <inline-formula><mml:math id="M308" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M309" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M310" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> model [Step 3.iii]</title>
      <p id="d2e4141">Figure 6 presents the results of the laboratory experiment conducted using TDR to calibrate the parameters of the Rhoades et al. (1976) model (also reported in Table 1). For each soil water content, ranging from 0.15 to 0.40 cm<sup>3</sup> cm<sup>−3</sup>, <inline-formula><mml:math id="M313" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> increases linearly with <inline-formula><mml:math id="M314" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> within a range of 1 to 9 dS m<sup>−1</sup>. The <inline-formula><mml:math id="M316" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values at different soil water content levels converge towards 0.13 dS m<sup>−1</sup> for topsoil and 0.07 dS m<sup>−1</sup> for subsoil.</p>

      <fig id="F6" specific-use="star"><label>Figure 6</label><caption><p id="d2e4237">Bulk electrical conductivity (<inline-formula><mml:math id="M319" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) measured by TDR vs. pore water electrical conductivity (<inline-formula><mml:math id="M320" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) measured by an EC meter for six levels of soil water content (cm<sup>3</sup> cm<sup>−3</sup>). The continuous lines represent the fitted Rhoades model (Eqs. 1 and 2) for <bold>(a)</bold> topsoil and <bold>(b)</bold> subsoil.</p></caption>
            <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f06.png"/>

          </fig>

      <p id="d2e4296">It's important to note that this relationship does not apply under dry soil conditions. In fact, the graphs show that as the water content decreases, the slope of the fitting line progressively flattens, becoming nearly horizontal at <inline-formula><mml:math id="M323" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.15</mml:mn></mml:mrow></mml:math></inline-formula> cm<sup>3</sup> cm<sup>−3</sup>. This suggests that <inline-formula><mml:math id="M326" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> becomes almost insensitive to changes in <inline-formula><mml:math id="M327" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> as the soil dries (Nadler, 1982; Rhoades et al., 1989). According to Nadler (2005), the relationship at low <inline-formula><mml:math id="M328" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> values becomes impractical due to the complex interdependencies between various solid- and liquid-phase parameters that dominate as water content decreases.</p>
      <p id="d2e4363">This finding is crucial for this study's focus on using EMI for salinity and water content assessment, as it indicates that EMI measurements should be conducted in wet or moderately wet soils rather than dry soils. Moreover, it highlights that a reasonable soil moisture threshold for reliable measurements in the studied soil is greater than 0.15 cm<sup>3</sup> cm<sup>−3</sup>.</p>
</sec>
</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Determination of <inline-formula><mml:math id="M331" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> distribution in non-saline plot [Step 4]</title>
      <p id="d2e4404">Figure 7 presents the <inline-formula><mml:math id="M332" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> values at four distinct depths (15, 50, 75, and 90 cm), derived from the soil-specific <inline-formula><mml:math id="M333" display="inline"><mml:mrow><mml:mi mathvariant="italic">θ</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) relationships detailed in Table 1 and correspond to the depths extracted from the image shown in Fig. 6c.</p>

      <fig id="F7"><label>Figure 7</label><caption><p id="d2e4431">Spatial distribution of soil water content (<inline-formula><mml:math id="M334" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>) in the non-saline plot at four depths (15, 50, 75, and 90 cm), estimated from bulk electrical conductivity (<inline-formula><mml:math id="M335" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) distribution.</p></caption>
          <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f07.png"/>

        </fig>

      <p id="d2e4458">At depths of 50, 75, and 90 cm, the <inline-formula><mml:math id="M336" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> data series nearly overlap, with average soil water content values 0.20 cm<sup>3</sup> cm<sup>−3</sup>. The variability at these depths is minimal, with an average coefficient of variation of 3.9 %. In contrast, the upper layer (15 cm) shows a higher average soil water content of 0.23 cm<sup>3</sup> cm<sup>−3</sup> and greater variability, with a coefficient of variation of 6.3 %. This suggests that deeper soil layers maintain more stable moisture conditions, while the upper horizon is more influenced by processes at boundary such as evaporation and infiltration.</p>
      <p id="d2e4511">Across all depths, higher values of soil water content are observed in the central part of the transect (7–12 m). This pattern corresponds to the higher <inline-formula><mml:math id="M341" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values shown in the data presented in Fig. 6c, indicating an increase in soil water content in this section of the plot across the different depths.</p>
</sec>
<sec id="Ch1.S3.SS4">
  <label>3.4</label><title>Estimation of <inline-formula><mml:math id="M342" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in the saline plot [Step 5]</title>
      <p id="d2e4545">Figure 8a shows the EC<sub>a</sub> measurements in both VCP and HCP modes for the three receiver coils <inline-formula><mml:math id="M344" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32, <inline-formula><mml:math id="M345" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71, and <inline-formula><mml:math id="M346" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118. The EC<sub>a</sub> values are higher than those observed in the non-saline plot, ranging from 0.2 to 0.45 dS m<sup>−1</sup>. Both VCP and HCP data display a similar pattern, with EC<sub>a</sub> values decreasing from the upper layer to the deeper layer, suggesting a more conductive topsoil, which is expected due to saline water irrigation. The differences are more pronounced in the VCP mode compared to the HCP mode. In terms of lateral variability, the EC<sub>a</sub> in vertical mode exhibits relatively minor variation, with coefficients of variation of 15 %, 14 %, and 13 % for <inline-formula><mml:math id="M351" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>118, <inline-formula><mml:math id="M352" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>71, and <inline-formula><mml:math id="M353" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>32, respectively. Additionally, higher EC<sub>a</sub> values are observed in the central part of the plot, gradually decreasing towards the edges. Despite the presence of the old buried channel crossing the plot, no noticeable differences in EC<sub>a</sub> are evident along this transect. This can be attributed to the dominant impact of soil salinity which masks the channel impact. The contribution of the channel is relatively minor (around 0.02 dS m<sup>−1</sup>), as previously observed in Fig. 6a.</p>

      <fig id="F8" specific-use="star"><label>Figure 8</label><caption><p id="d2e4672">Apparent soil electrical conductivity (EC<sub>a</sub>) along the transect for the saline plot: <bold>(a)</bold> HCP mode; <bold>(b)</bold> VCP mode. Points indicate measured EC<sub>a</sub>, while dashed lines show the calculated EC<sub>a</sub> (forward response of the inversion). <bold>(c)</bold> Inversion results showing the bulk electrical conductivity (<inline-formula><mml:math id="M360" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) distribution with depth.</p></caption>
          <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f08.png"/>

        </fig>

      <p id="d2e4729">Figure 8c shows the <inline-formula><mml:math id="M361" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> distribution obtained from the inversion procedure of the EMI measurements conducted on 2 August in the saline plot. The model response was shown in Fig. 8a, b by dashed lines. The misfit error is 0.03 dS m<sup>−1</sup>, indicating a fairly good fit between the observed data and model responses. The misfit is slightly higher than the one observed in non-saline soil, due to greater EC<sub>a</sub> values and variability range. As expected, the values of <inline-formula><mml:math id="M364" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> obtained from the inversion modelling were consistently higher in the saline plot compared to the non-saline plot. These values decreased from the surface to a depth of two metres, ranging from 0.55 to 0.10 dS m<sup>−1</sup>. This pattern of declining <inline-formula><mml:math id="M366" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> with depth has also been reported by other authors (e.g., Saeed et al., 2017). During the irrigation season, salt accumulation tends to be concentrated in the topsoil layer (Coppola et al., 2015, 2016), largely due to evaporation at the soil surface, which causes salts to rise and concentrate in the upper layers (Corwin and Lesch, 2005; Kara and Willardson, 2006).</p>
      <p id="d2e4800">The Rhoades model was applied to estimate the electrical conductivity of the soil solution based on the <inline-formula><mml:math id="M367" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> measurements obtained from the EMI for both horizons. The laboratory calibrations provided the parameters <inline-formula><mml:math id="M368" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M369" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M370" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (as shown in Table 1), while <inline-formula><mml:math id="M371" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> was assumed as the average value measured in the non-saline plot (an average value for each of the four depths, as seen in Fig. 7). In addition, to account for the variability of water content in the non-saline plot – and consequently, the error associated with its estimation, which influences the <inline-formula><mml:math id="M372" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> estimation procedure – the analysis was also conducted by using the mean water content value plus or minus its standard deviation. In this way, the validity of using the average value of the non-saline plot was numerically tested and further supported by additional considerations discussed in Sect. 3.5.</p>
</sec>
<sec id="Ch1.S3.SS5">
  <label>3.5</label><title>Validation of <inline-formula><mml:math id="M373" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M374" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula></title>
<sec id="Ch1.S3.SS5.SSS1">
  <label>3.5.1</label><title><inline-formula><mml:math id="M375" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>: estimated by EMI (<inline-formula><mml:math id="M376" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) vs. soil solution (1 : 2) extract (<inline-formula><mml:math id="M377" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) [Step 6.i]</title>
      <p id="d2e4935">Validation of the soil electrical conductivity estimated by EMI, <inline-formula><mml:math id="M378" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, was carried out by comparing it with soil solution electrical conductivities measurements, <inline-formula><mml:math id="M379" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>. Figure 9 illustrates the results for four depths: 15, 50, 75, and 90 cm. In the figures, the data series for <inline-formula><mml:math id="M380" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are represented by continuous lines, while <inline-formula><mml:math id="M381" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> values are shown as squares. To account for small-scale heterogeneity in <inline-formula><mml:math id="M382" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> – arising from the differing observation scales of the two data series – a simple moving average filter was applied to smooth the <inline-formula><mml:math id="M383" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> data. As a result, the influence of individual measurements (short-term fluctuations) was minimized, while preserving the overall trend along the transect (long-term fluctuations) (Dragonetti et al., 2018; Western and Blöschl, 1999).</p>

      <fig id="F9" specific-use="star"><label>Figure 9</label><caption><p id="d2e5037">Spatial distribution of <inline-formula><mml:math id="M384" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> within the trench at four depths (15, 50, 75 and 90 cm). The continuous lines represent <inline-formula><mml:math id="M385" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, while the squares indicate the measured <inline-formula><mml:math id="M386" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> after applying a filtering process. The dotted lines denote the variability range of <inline-formula><mml:math id="M387" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, computed based of one standard deviation of <inline-formula><mml:math id="M388" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> as measured in the non-saline plot.</p></caption>
            <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f09.png"/>

          </fig>

      <p id="d2e5112">The largest discrepancies between measured and estimated <inline-formula><mml:math id="M389" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values occur at a depth of 15 cm, with significant scatter around the mean (RMSE <inline-formula><mml:math id="M390" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 2.15 dS m<sup>−1</sup>) and a relatively high overestimation (bias <inline-formula><mml:math id="M392" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.57 dS m<sup>−1</sup>). At the other three depths, the data show better agreement, with RMSE values below 1.33 dS m<sup>−1</sup> and bias ranging from <inline-formula><mml:math id="M395" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.37</mml:mn></mml:mrow></mml:math></inline-formula> to 1.13 dS m<sup>−1</sup>.</p>
      <p id="d2e5200">As depth increases, the correlation coefficient between the two series rises from 0.10 in the upper layer to 0.87 in the deeper layer. The graphs in Fig. 9 also show the <inline-formula><mml:math id="M397" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> estimates obtained by assuming, at each depth considered, the average plus/minus the standard deviation of the water contents measured under the non-saline transect (dotted lines). Note that the uncertainty in the <inline-formula><mml:math id="M398" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> estimations coming from the assumption of similarity between the two plots in terms of water contents is quite high only for the data at 15 cm. This uncertainty decreases markedly with depth, likely due to reduced variability in soil water content. This issue is discussed in detail later in a dedicated section.</p>
      <p id="d2e5235">As suggested by Robinet et al. (2018) who analysed the reasons behind discrepancies in <inline-formula><mml:math id="M399" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> detected by sensors operating at different observation volumes – similar to our case – the weak correlation between EMI and soil sampling measurements for a shallow sensing coil configuration and the forward-calculated EC<sub>a</sub> can be attributed to several factors. Firstly, significant variations in <inline-formula><mml:math id="M401" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> near the soil surface may not be effectively captured by local soil sampling. Secondly, the uneven and irregular nature of the soil surface can significantly impact EMI measurements. Variations in elevation and rough terrain make it difficult for the operator to keep the instrument at a constant height above the ground. Since EMI measurements are highly sensitive to the distance between the sensor and the soil, any fluctuations in height can introduce inconsistencies in the data, potentially affecting the accuracy and reliability of the results. Thirdly, <inline-formula><mml:math id="M402" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> measurements are influenced by the maize root system, which is denser in the shallower soil layer, further impacting the readings. These factors contribute to the relatively high variance observed at 15 cm in EMI measurements (<inline-formula><mml:math id="M403" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>), which decreases with depth (see Table 2). By contrast, the same table shows that the variance <inline-formula><mml:math id="M404" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> remains roughly constant, with a slight decrease toward depth.</p>

<table-wrap id="T2"><label>Table 2</label><caption><p id="d2e5316">Values of variance for the <inline-formula><mml:math id="M405" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> measurement by EMI, <inline-formula><mml:math id="M406" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, soil solution, <inline-formula><mml:math id="M407" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and filtered soil solution data.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="3">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Depth</oasis:entry>
         <oasis:entry namest="col2" nameend="col3" align="center">Variance </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">[cm]</oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col3" align="center">[dS<sup>2</sup> m<sup>−2</sup>] </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M410" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M411" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">SS</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">15</oasis:entry>
         <oasis:entry colname="col2">3.41</oasis:entry>
         <oasis:entry colname="col3">1.60</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">50</oasis:entry>
         <oasis:entry colname="col2">2.41</oasis:entry>
         <oasis:entry colname="col3">1.64</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">75</oasis:entry>
         <oasis:entry colname="col2">1.39</oasis:entry>
         <oasis:entry colname="col3">1.41</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">90</oasis:entry>
         <oasis:entry colname="col2">0.84</oasis:entry>
         <oasis:entry colname="col3">1.36</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S3.SS5.SSS2">
  <label>3.5.2</label><title>EMI vs. TDR (saline plot) [Step 6.ii]</title>
      <p id="d2e5513">The procedure was further validated by comparing the soil water content estimated by EMI with an independent series of water content measurements taken by TDR in the saline plot immediately after the EMI readings. While this comparison was not strictly required for the procedure, it serves to corroborate the assumptions and findings discussed. In fact, the concept of validation has a twofold meaning. On one hand, it allows us to assess whether the estimated values, obtained through the six-step procedure outlined in Fig. 1, align with the measured ones. On the other hand, it verifies whether the value estimated from the non-saline plot effectively corresponds to the one measured in the same plot. Additionally, validation provides insights into the variability of the estimate compared to the actual measurements.</p>
      <p id="d2e5516">Figure 10 presents the data series for soil water content estimated by EMI (<inline-formula><mml:math id="M412" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), derived from EMI measurements following the outlined procedure, shown as continuous lines. Alongside these, the measured water content values from TDR (<inline-formula><mml:math id="M413" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">TDR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) are represented by filled squares. Each panel in Fig. 10 also includes statistical parameters <inline-formula><mml:math id="M414" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula> root mean square error (RMSE), bias, and correlation coefficient (<inline-formula><mml:math id="M415" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula>) <inline-formula><mml:math id="M416" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula> which assess the agreement between the <inline-formula><mml:math id="M417" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M418" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">TDR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> series.</p>

      <fig id="F10" specific-use="star"><label>Figure 10</label><caption><p id="d2e5587">Spatial distribution of soil water content within the trench for four depths (15, 50, 75 and 90 cm) as measured by TDR (<inline-formula><mml:math id="M419" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">TDR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and estimated by EMI, (<inline-formula><mml:math id="M420" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) in the non-saline transect. The <inline-formula><mml:math id="M421" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">TDR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> data are represented by empty square. <inline-formula><mml:math id="M422" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> data for each position are represented by a continuous thick solid line. Horizon-wise mean of <inline-formula><mml:math id="M423" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> value is represented by a thin solid line while dashed lines represents the horizon-wise <inline-formula><mml:math id="M424" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> mean <inline-formula><mml:math id="M425" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SD.</p></caption>
            <graphic xlink:href="https://soil.copernicus.org/articles/12/37/2026/soil-12-37-2026-f10.png"/>

          </fig>

      <p id="d2e5671">The water content at each depth remains approximately constant throughout the transect, indicating notable homogeneity in the horizontal plane. This observation supports the fundamental hypothesis of the study. Across the four depths, the average values of <inline-formula><mml:math id="M426" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> ranged between 0.20 and 0.23 cm<sup>3</sup> cm<sup>−3</sup>, with a mean error (RMSE) of 0.02 cm<sup>3</sup> cm<sup>−3</sup> and a slight underestimation whit a BIAS value of <inline-formula><mml:math id="M431" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.008</mml:mn></mml:mrow></mml:math></inline-formula> cm<sup>3</sup> cm<sup>−3</sup>.</p>
      <p id="d2e5759">A weak correlation was observed in the topsoil, where the correlation coefficient between <inline-formula><mml:math id="M434" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">EMI</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M435" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">TDR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> was low, with values of <inline-formula><mml:math id="M436" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.15</mml:mn></mml:mrow></mml:math></inline-formula> and 0.24 at depths of 15 and 50 cm, respectively. In contrast, a strong correlation was observed in the subsoil at depths of 75 and 90 cm, with <inline-formula><mml:math id="M437" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> values of 0.88 and 0.89, respectively. This trend of increasing correlation from topsoil to subsoil is consistent with previous studies, such as Calamita et al. (2015), which reported similar patterns.</p>
      <p id="d2e5803">The dotted lines in the four plots of Fig. 10 represent the range of variability of <inline-formula><mml:math id="M438" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mi mathvariant="normal">w</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">EMI</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, calculated adding and subtracting the standard deviation (SD) of <inline-formula><mml:math id="M439" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> from the values measured in the non-saline plot for each layer. These two lines help to quantify the impact of using the average <inline-formula><mml:math id="M440" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> obtained at different depths in the non-saline transect when analysing data from the saline transect.</p>
      <p id="d2e5836">Regarding correlation and RMSE, the impact of soil water content variability on the <inline-formula><mml:math id="M441" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> estimate decreases with increasing measurement depth. At 15 cm the effect is relatively pronounced, whereas at greater depths it becomes negligible. This finding underscores the robustness of the obtained values, with minimal uncertainty at deeper layers. However, at 15 cm the estimates are less reliable. In fact, various studies have highlighted the impact of <inline-formula><mml:math id="M442" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> variability on soil salinity estimation, particularly within the root zone, where significant fluctuations in <inline-formula><mml:math id="M443" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> occur due to irrigation practices and evaporation (e.g., Gómez Flores et al., 2022; Paz et al., 2020).</p>
</sec>
</sec>
<sec id="Ch1.S3.SS6">
  <label>3.6</label><title>Limits and conditions of use of the procedure</title>
      <p id="d2e5873">The procedure assumes that, on the surveys date, the average horizon-wise soil water content in the saline plot is similar to that in the non-saline plot. In the context of our case study, this assumption is supported by the following considerations: <list list-type="custom"><list-item><label>1.</label>
      <p id="d2e5878">Pedo-hydrological similarity:</p>
      <p id="d2e5881">A study by Bonfante et al. (2019) conducted at the same site demonstrated the pedo-hydrological similarity between the two plots. Their Fig. 2 illustrates that the soils and horizons in both plots exhibit very similar hydrological and physical properties.</p></list-item><list-item><label>2.</label>
      <p id="d2e5885">Identical field management:</p>
      <p id="d2e5888">Throughout the growing season, both plots were managed identically: <list list-type="custom"><list-item><label>–</label>
      <p id="d2e5893">They received the same irrigation volumes and followed the same irrigation schedule.</p></list-item><list-item><label>–</label>
      <p id="d2e5897">Maize was sown on the same day in both plots.</p></list-item><list-item><label>–</label>
      <p id="d2e5901">The first saline irrigation was applied on 6 June  – approximately 50 d after sowing (16 April) – to prevent early stress and minimize its impact on crop development.</p></list-item><list-item><label>–</label>
      <p id="d2e5905">Physiological measurements, including phenological phase and root depth, were comparable across both plots.</p></list-item></list></p></list-item><list-item><label>3.</label>
      <p id="d2e5909">Water Uptake and Crop Response: <list list-type="custom"><list-item><label>–</label>
      <p id="d2e5914">Leaf water potential measurements showed no significant differences throughout the irrigation. A <inline-formula><mml:math id="M444" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>-test confirmed the absence of significant differences between the plots (<inline-formula><mml:math id="M445" display="inline"><mml:mrow><mml:mi>p</mml:mi><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0.05</mml:mn></mml:mrow></mml:math></inline-formula>), indicating similar water uptake conditions.</p></list-item></list></p></list-item></list></p>
      <p id="d2e5936">In summary, given the nearly identical soil and sequence of soil horizons, their corresponding hydraulic properties, and the identical irrigation regime, it is reasonable to assume that the mean water content in each horizon on the survey date is similar in both plots. This assumption is further supported by the mostly overlapping water uptake and physiological status of maize during the irrigation season. Consistently with this assumption, the horizon-wise mean <inline-formula><mml:math id="M446" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> required by the Rhoades model was obtained in the non-saline plot from EMI via the site-specific <inline-formula><mml:math id="M447" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>–<inline-formula><mml:math id="M448" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> calibration. A concurrent experiment at the same experimental farm (Bonfante et al., 2019) collected a single vertical TDR profile in the non-saline plot on the survey date. The measured <inline-formula><mml:math id="M449" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> values on these surveys were consistent with the EMI-derived horizon-wise means; however, this profile is not presented here because its spatial representativeness is limited and its inclusion would not affect the analyses or conclusions.</p>
      <p id="d2e5971">In a context of relative soil homogeneity and similar agricultural management, the procedure yielded satisfactory results. Therefore, the procedure effectiveness diminishes when applied on a larger scale or to heterogeneous soil conditions. In addition, accuracy is expected to be lower in the upper 10–20 cm where EMI sensitivity decreases and near-surface <inline-formula><mml:math id="M450" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> dynamics are stronger.</p>
      <p id="d2e5981">However, if the experimental conditions revealed at the site here described are not available, the applicability of the method may be challenged. In such cases, adjustments would help ensure the reliability and robustness of the procedure in different environmental and agronomic contexts. Specifically, when a twin of non-saline plot is not available, the horizon-wise mean <inline-formula><mml:math id="M451" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> on the survey date can be obtained directly in the field using a small set of moisture probes placed in homogeneous zones identified by a preliminary EC<sub>a</sub> map. Moreover, EMI shortly after irrigation/rainfall further reduces <inline-formula><mml:math id="M453" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> contrasts.</p>
      <p id="d2e6008">In principle, the procedure is specifically designed for soils experiencing secondary salinization due to irrigation, which facilitates the identification of similar non-saline soils on the same farm. Applying this procedure to soils with primary salinization is more challenging, due to the absence of such reference conditions. Nevertheless, this limitation is partially addressable. The average soil water content for each layer could be independently measured using alternative methods and applied directly to the saline plot, thereby eliminating the need for a reference non-saline plot. For instance, installing a network of soil moisture probes adequately calibrated and strategically placed across the field could provide the necessary data to apply the proposed methodology. In this case, the adequate placement of soil moisture sensors plays a crucial role in ensuring the representativeness and accuracy of the measurements. Variability field maps derived from EC<sub>a</sub> measurements could be used preliminary to identify zones with homogeneous soil properties and the sensors could be strategically positioned within these zones to capture a comprehensive profile of soil water content required to apply the proposed procedure extensively throughout the field. In such applications, uncertainty can be transparently conveyed by propagating the horizon-wise <inline-formula><mml:math id="M455" display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> mean <inline-formula><mml:math id="M456" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SD used in the inversion. This solution could be broadening the potential applicability of the procedure to other contexts, eliminating the need for a non-saline plot and considering the soils spatial variability.</p>
</sec>
</sec>
<sec id="Ch1.S4" sec-type="conclusions">
  <label>4</label><title>Conclusions</title>
      <p id="d2e6043">This study introduces a novel procedure for quickly distinguishing the contributions of water content and salinity in electromagnetic induction (EMI) measurements of apparent electrical conductivity (EC<sub>a</sub>) providing a valuable tool for soil and water management. EC<sub>a</sub> measurements were conducted along two adjacent parallel transects: one irrigated with non-saline water and the other with saline water. Electrical conductivity levels of 1 dS m<sup>−1</sup> (considered the non-saline level) and 8 dS m<sup>−1</sup> were utilized for comparison.</p>
      <p id="d2e6088">The proposed procedure is based on the hypothesis that the average soil water content in the saline transect is “similar” to that in the adjacent non-saline transect. Given the similar soil physical properties, hydrology, irrigation distribution, and fertilization practices expected in both transects, we anticipate comparable agronomic conditions. This can lead to similar root distributions and nutrient uptake patterns, ultimately resulting in analogous water content distributions. Our findings support the validity of this hypothesis, as evidenced by the strong correlation between <inline-formula><mml:math id="M461" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> estimated via EMI and <inline-formula><mml:math id="M462" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> measured directly from soil solutions extracted from samples.</p>
      <p id="d2e6113">When the hypothesis holds, the proposed procedure is relatively straightforward to implement, addressing a key challenge in EMI application, distinguishing the effects of soil water content and salinity. To the best of our knowledge, this represents the first field-scale attempt to differentiate these effects in EMI measurements.</p>
      <p id="d2e6116">Despite the promising results, certain limitations must be acknowledged. Firstly, the underlying assumption of similar average soil water content limits the applicability of the proposed procedure, and, therefore, the procedure's effectiveness diminishes when applied on a larger scale or to heterogeneous soil conditions. Secondly, the procedure is specifically designed for soils experiencing secondary salinization due to irrigation, which facilitates the identification of similar non-saline soils on the same farm. Applying this procedure to soils affected by primary salinization is more challenging, because a comparable non-saline reference plot is typically unavailable.</p>
      <p id="d2e6120">Finally, the reliability of the EMI method tends to diminish at the soil surface, which can lead to less accurate results. however, with the fast development of EMI sensors equipped with a greater number of receivers and/or frequencies, the accuracy of EMI at soil surface may improve to some extent.</p>
      <p id="d2e6123">Future research should aim to validate the hypothesis of similar water content distribution in shallower soil layers, which often exhibit more erratic dynamics and less consistent results. To enhance this validation, the proposed procedure could be integrated with simulations of soil water flow using hydrological models, alongside appropriate top boundary conditions applied in the field experiment.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d2e6132">Data can be made available from the corresponding author upon request.</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d2e6138">DA: Conceptualization, Data curation, Formal analysis, Investigation, Visualization, Writing (original draft preparation), Writing (review and editing). AC: Conceptualization, Supervision, Writing (review and editing). RDM: Data curation, Investigation. MF: Conceptualization, Data curation, Formal analysis, Investigation, Writing (review and editing). AB: Conceptualization, Data curation, Investigation, Supervision, Writing (original draft preparation), Writing (review and editing).</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d2e6144">The contact author has declared that none of the authors has any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d2e6150">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. The authors bear the ultimate responsibility for providing appropriate place names. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.</p>
  </notes><notes notes-type="sistatement"><title>Special issue statement</title>

      <p id="d2e6156">This article is part of the special issue “Agrogeophysics: illuminating soil's hidden dimensions”. It is not associated with a conference.</p>
  </notes><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d2e6162">This research was performed within the project “SALTFREE: Salinization in irrigated areas: risk evaluation and prevention”, funded by the MIPAAF (Ministry of Agriculture) under the call ARIMNET2.</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d2e6168">This paper was edited by David O'Leary and reviewed by two anonymous referees.</p>
  </notes><ref-list>
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